108429-82-9Relevant academic research and scientific papers
Intramolecular Amidoselenation of N-Alkenyl Imidates to N-Heterocycles
Terao, Keiji,Toshimitsu, Akio,Uemura, Sakae
, p. 1837 - 1844 (2007/10/02)
The reactions of N-alkenyl imidates with benzeneselenenyl chloride and bromide in chloroform at ambient temperature afford pyrrolidine and piperidine derivatives having a phenylseleno moiety in good to excellent yields under neutral conditions.The key step of this new reaction consists of an intramolecular carbon-nitrogen bond formation and a simultaneous carbon-oxygen bond fission.
