108448-46-0

Basic information

• Product Name: (-)-(S)-2,2,4-trimethyl-3-cyclohexene-1-methanol
• Synonyms: (-)-(S)-2,2,4-trimethyl-3-cyclohexene-1-methanol
• CAS NO: 108448-46-0
• Molecular Weight: 154.252
• Mol File: 108448-46-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (-)-(S)-2,2,4-trimethyl-3-cyclohexene-1-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(S)-2,2,4-trimethyl-3-cyclohexene-1-methanol(108448-46-0)
• EPA Substance Registry System: (-)-(S)-2,2,4-trimethyl-3-cyclohexene-1-methanol(108448-46-0)

Safety Data

• Hazardous Substances Data: 108448-46-0(Hazardous Substances Data)

Upstream product

• 79400-60-5 (-)-(S)-2,2,4-trimethyl-3-cyclohexene-1-carbaldehyde 
• 55695-33-5 (2,2,4-trimethyl-3-cyclohexen-1-yl)methanol 
• 127075-63-2 acetic acid-(2,2,4-trimethyl-cyclohex-3-enylmethyl ester) 
• 127075-63-2 Acetic acid (S)-2,2,4-trimethyl-cyclohex-3-enylmethyl ester 
• 473-67-6 trans-verbenol 
• 19890-04-1 (-)-Essigsaeure-(trans-verbenyl)ester 
• 108394-25-8 (+)-Essigsaeure-(cis-pin-3-en-2-yl)ester 

Downstream Products

• 326907-23-7 (E)-3-((S)-2,2,4-Trimethyl-cyclohex-3-enylmethoxy)-acrylic acid methyl ester 
• 89888-03-9 (E,2S,6R)-(-)-cis-α-irone 
• 139406-58-9 (E)-3-((1R,5S)-2,5,6,6-Tetramethyl-cyclohex-2-enyl)-acrylic acid 
• 326907-32-8 (E)-3-((1R,3S)-2,2,3-Trimethyl-6-methylene-cyclohexyl)-acrylic acid 
• 326907-26-0 (E)-3-((1R,5S)-5-Hydroxymethyl-2,6,6-trimethyl-cyclohex-2-enyl)-acrylic acid 
• 326907-31-7 (E)-3-((1R,3S)-3-Hydroxymethyl-2,2-dimethyl-6-methylene-cyclohexyl)-acrylic acid 

Relevant articles and documents

Synthesis of both enantiomers of cis-α-irone and cis-γ-irone, principal constituents of iris oil, via resolution of (±)-2,2,4-trimethyl-3-cyclohexene-1-carboxylic acid

The principal constituents of iris oil, (-)-cis-α-irone and (-)-cis-γ-irone, and their enantiomers, were synthesized from (-)- and (+)-2,2,4-trimethyl-3-cyclohexene-1-carboxylic acids. The racemic acid was resolved by recrystallization of its salt with a chiral amine, or by enzymatic hydrolysis of the corresponding alcohol. The fragrances of (-)-(1R,5S)-cis-α-irone and (-)-(1R,5S)-cis-γ-irone were superior to those of (+)-(1S,5R)-cis-α-irone and (+)-(1S,5R)-cis-γ-irone. Copyright (C) 2000 Elsevier Science Ltd.