1084820-36-9

Basic information

• Product Name: (R)-1-benzyl-2,2-dimethoxyethylamine
• Synonyms: (R)-1-benzyl-2,2-dimethoxyethylamine
• CAS NO: 1084820-36-9
• Molecular Weight: 195.261
• Mol File: 1084820-36-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R)-1-benzyl-2,2-dimethoxyethylamine(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-benzyl-2,2-dimethoxyethylamine(1084820-36-9)
• EPA Substance Registry System: (R)-1-benzyl-2,2-dimethoxyethylamine(1084820-36-9)

Safety Data

• Hazardous Substances Data: 1084820-36-9(Hazardous Substances Data)

Upstream product

• 1403991-04-7 (R)-1-benzyl-2,2-dimethoxyethylammonium N-acetyl-(L)-phenylalaninate 
• 1184944-94-2 (R)-1-benzyl-2,2-dimethoxyethylammonium N-acetyl-L-phenylalaninate 
• 1217341-14-4 C₁₈H₂₃NO₂ 
• 10172-89-1 (R)-N-acetylphenylalanin 
• 55707-43-2 1-benzyl-2,2-dimethoxyethylamine 

Downstream Products

• 1084820-37-0 1,1-dimethoxy-3-phenylpropan-2-one oxime 

Relevant articles and documents

Resolution and absolute configuration of some a-aminoacetals: En route to enantiopure N-protected a-aminoaldehydes

The first successful resolution of rac-a-aminoacetals via diastereoisomeric salt formation with optically pure N-protected aminoacids is reported. The absolute configuration assignment of a-aminoacetal enantiomers is performed by an entirely non-racemizing chemical correlation method involving N-protection and a new efficient hydrolysis step followed by a reduction of the resulting N-protected a-aminoaldehyde intermediates. A racemization method of optically enriched a-aminoacetals is exemplified to allow valorisation of both enantiomers. Springer-Verlag 2011.

PROCESS OF RACEMISATION OF OPTICALLY ACTIVE ALPHA AMINOACETALS

The invention relates to a process for preparing α-aminoacetals substantially in racemic form, comprising a step of oxidizing optically enriched α-aminoacetals to the corresponding oximes, in the presence of a catalyst, and a step of reducing the oximes t