1084920-51-3

Basic information

• Product Name: [Ni(II)(μ-OH2)(e,a-cis-cyclohexane-1,2-dicarboxylate)]
• CAS NO: 1084920-51-3
• Molecular Weight: 246.87
• Mol File: 1084920-51-3.mol

Chemical Properties

• CAS DataBase Reference: [Ni(II)(μ-OH2)(e,a-cis-cyclohexane-1,2-dicarboxylate)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ni(II)(μ-OH2)(e,a-cis-cyclohexane-1,2-dicarboxylate)](1084920-51-3)
• EPA Substance Registry System: [Ni(II)(μ-OH2)(e,a-cis-cyclohexane-1,2-dicarboxylate)](1084920-51-3)

Safety Data

• Hazardous Substances Data: 1084920-51-3(Hazardous Substances Data)

Upstream product

• 610-09-3 (1R,2S)-cyclohexane-1,2-dicarboxylic acid 
• 7732-18-5 water 

Relevant articles and documents

Probing single-chain magnets in a family of linear chain compounds constructed by magnetically anisotropic metal-ions and cyclohexane-1,2- dicarboxylate analogues

Five new metal-carboxylate chain-based laminated compounds, namely, ∞2[FeII(e,e-trans-1,2-chdc)] (3) (1,2-chdc = cyclohexane-1,2-dicarboxylate), ∞ 2[NiII(μ-OH2)(e,a-cis-1,2-chdc)] (4), ∞2[CoII(μ-OH2)(1,2-chedc)] (5) (1,2-chedc = cyclohex-1-ene-1,2-dicarboxylate), ∞ 2[Co5II(μ3-OH)2(OH 2)2(1,2-chedc)4] (6), and ∞2[CoII(4-Me-1,2-chdc)] (7) (4-Me-1,2-chdc = trans-4-methylcyclohexane-1,2-dicarboxylate) have been hydrothermally synthesized. In these series of magnetic chain-based compounds, 3 and 7 have the same dimeric paddle-wheel M(II)-carboxylate chain as the previously reported compound, ∞2[Co II(trans-1,2-chdc)] (2). However, compound 3 does not behave as a single-chain magnet (SCM) but simply an alternating ferro-antiferro magnetic chain. Compound 4 has the cis conformation of 1,2-chdc ligand, which leads to a uniform aqua-carboxylate-bridged Ni(II) chain. Such a Ni-O chain exhibits strong antiferromagnetic interactions, leading to a diamagnetic ground state. Compound 5 features a corner-sharing triangular chain, or Δ-chain, which is part of a Kagome lattice. However, 5 does not exhibit a spin-frustrated effect but simply spin competition. Compound 6 has a unique pentanuclear Co II cluster, which is further connected by the syn-anti carboxylate into a chain structure. Compound 6 exhibits antiferromagnetic interactions among the Co(II) ions, and no SCM behavior is observed. These results might indicate that the dimeric paddle-wheel Co(II)-carboxylate chain is essential in obtaining SCM behavior in this family of compounds. Although 2 and 7 have very similar SCM behavior, alternating current magnetic studies show that 7 has a higher energy barrier than that of 2. Such behavior is probably caused by the larger anisotropic energy barrier in 7.