1085293-60-2Relevant academic research and scientific papers
Totally regio- and stereoselective behavior of mono- and diactivated cyclic alkenes in the Lu reaction: Synthesis of enantiopure functionalized cyclopentanes
Garcia Ruano, Jose L.,Nunez Jr., Alberto,Martin, M. Rosario,Fraile, Alberto
, p. 9366 - 9371 (2008)
(Chemical Equation Presented) 5-Alkoxyfuran-2(5H)-ones optically pure 3-p-tolylsulfinyl derivatives, synthetic equivalents of the acyclic esters, react with dipoles generated from allenoates and PPh3 (Lu reaction), in a completely regioselective, π-facial selective and endo-selective manner, yielding bicyclic adducts, which are easily converted into optically pure highly substituted cyclopentane derivatives.
