108533-50-2Relevant academic research and scientific papers
Ionic liquid as catalyst and reaction medium: A simple, convenient and green procedure for the synthesis of thioethers, thioesters and dithianes using an inexpensive ionic liquid, [pmIm]Br
Ranu, Brindaban C.,Jana, Ranjan
, p. 1811 - 1818 (2007/10/03)
An easily accessible and inexpensive room temperature ionic liquid, 1-pentyl-3-methylimidazolium bromide, [pmIm]Br efficiently catalyzes the reaction of alkyl halides or acyl halides with thiols without any solvent at room temperature leading to the synthesis of thioethers and thioesters in high yields. This reaction has also been extended for the preparation of dithianes and transthioetherification. The ionic liquid is recovered and recycled for subsequent runs.
Addition of Organometallic Reagents to Cyclooctenyl Phenyl Sulfones
Hardinger, Steven A.,Fuchs, P. L.
, p. 2739 - 2749 (2007/10/02)
A series of cyclooctenyl and cyclooctadienyl phenyl sulfones were prepared and exposed to various organometallic reagents.The regio- and stereochemical results of these reactions are outlined below.The cuprate-induced reduction of epoxy vinyl sulfones 17 and 29 was explored; a mechanism involving two one-electron transfers was implicated.
NUCLEOPHILIC ADDITION TO COORDINATED ALLYL LIGANDS. HETEROATOM NUCLEOPHILES WITH CATIONIC MOLYBDENUM COMPLEXES
Vanarsdale, W. E.,Winter, R. E. K.,Kochi, J. K.
, p. 31 - 54 (2007/10/02)
The addition of the heteronuclear anions (methoxide, hydride, alkylnitronate and mercaptide) to a series of ?-allylmolybdenum cations, related to η5-C5H5Mo(CO)(NO)(η3-alyl)+ was examined.In each case, the adducts derived f
