108546-02-7Relevant academic research and scientific papers
Preparation method of substituted aryl porphyrin
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Paragraph 0062-0065, (2019/07/04)
The invention provides a preparation method of substituted aryl porphyrin. The method comprises the following steps that a, aromatic aldehyde shown in the formula (1) is dissolved in a reaction solvent to obtain a dissolving solution; b, pyrrole is dropwi
meso-Substituted Porphyrins, 4
Volz, Heinrich,Hassler, Michael,Schaeffer, Hermann
, p. 1265 - 1272 (2007/10/02)
2-Pyrryl-(3,5-dimethylphenyl)-carbinol, 2-pyrryl-(3,5-di-t-butyl-phenyl)-carbinol and 2-pyrryl-mesityl-carbinol are cyclised in acidic medium to the corresponding meso-tetraarylporphyrins.The meso-tetraarylporphyrins are transfered to the iron complexes.The reactions of the iron-porphyrins with OH(-) and H3CO(-) are studied and the products of these reactions are characterised. - Keywords: meso-Tetraarylporphyrins, meso-Tetraarylporphinatoiron(III) Complexes, meso-Tetramesitylporphinatoiron(III)methoxide, meso-Tetraarylporphinatoiron(III)hydroxides, μ-Oxo-bis(meso-tetraarylporphinatoiron(III))
IMROVED METHOD FOR SYNTHESIS OF SUBSTUTUTED TETRAPHENYLPORPHINS
Semeikin, A. S.,Koifman, O. I.,Berezin, B. D.
, p. 629 - 632 (2007/10/02)
Condensation of pyrrole with benzaldehydes in a mixture of xylene and chloroacetic acid gives a series of substituted tetraphenylporphins with yields exeeding the yields of porphyrins synthetized according to known preparative methods.
