1085523-97-2Relevant academic research and scientific papers
Intermolecular reaction of internal alkynes and imines: Propargyl tosylates as key partners in a gold-catalyzed [4 + 1] unusual cyclization leading to cyclopent-2-enimines
Suarez-Pantiga, Samuel,Rubio, Eduardo,Alvarez-Rua, Carmen,Gonzalez, Jose M.
supporting information; experimental part, p. 13 - 16 (2009/07/04)
Propargyl tosylates react with N-tosylaldimines to afford cyclopent-2-enimines in a gold-catalyzed process that involves a deep reorganization of both substrates. The formal [4 + 1] cyclization is initiated by a 1,2-migration of the tosylate that eventual
