108572-99-2Relevant academic research and scientific papers
Reactivite des cinnamoyl-3 pyrones-2 vis a vis des amines primaires
Chergui, Djamel,Hamdi, Haamar,Baboulene, Michel,Speziale, Vincent,Lattes, Armand
, p. 1721 - 1724 (2007/10/02)
The reaction of primary amines (methylamine, isopropylamine, benzylamine) in neutral medium, on 3-cinnamoyl-2-pyrones gave 7-amino-3,5-dioxo-1,6-octadienes 2.The formation of these compounds is presumed to occur via nucleophilic attack of amines with a ring opening reaction followed by decarboxylation.Their structures were determined unambiguously by 1H, 13C nmr spectroscopy, elemental analysis and mass spectrometry.
