108574-22-7

Upstream product

• 108574-25-0 (4-Bromo-phenylazo)-(4-chloro-phenyl)-methyl-hydroperoxide 
• 108574-25-0 (4-Bromo-phenylazo)-(4-chloro-phenyl)-methyl-hydroperoxide 

Relevant academic research and scientific papers

Activation of Molecular Oxygen into Hydrogen Peroxide via α-Azobenzyl Hydroperoxide. A Generation of Hydrogen Peroxide from Organic Hydroperoxide by the Amine-base Catalyzed Reaction

Hydrogen peroxide is generated together with nitrile imine from α-azobenzyl hydroperoxide, which is formed readily by autooxidation of arylaldehyde hydrazone, via peroxycarboximidic acid by the amine-base catalyzed reaction in benzene.This provides a new type of activation reaction of molecular oxygen into hydrogen peroxide by aldehyde hydrazone.

FORMATION AND REACTION OF N-SUBSTITUTED PEROXYCARBOXIMIDIC ACIDS FROM α-AZOBENZYL HYDROPEROXIDES BY PYRIDINE-CATALYZED REACTION

α-Azobenzyl hydroperoxides (4) isomerize to N-(4-bromoanilino)-peroxycarboximidic acids (5), which are transformed into benzoic acids (6), by the pyridine-catalyzed reaction.