108579-54-0

Basic information

• Product Name: α-(trimethylsilyl)benzyl trimethylsilylmethyl sulfide
• CAS NO: 108579-54-0
• Molecular Weight: 282.597
• Mol File: 108579-54-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: α-(trimethylsilyl)benzyl trimethylsilylmethyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: α-(trimethylsilyl)benzyl trimethylsilylmethyl sulfide(108579-54-0)
• EPA Substance Registry System: α-(trimethylsilyl)benzyl trimethylsilylmethyl sulfide(108579-54-0)

Safety Data

• Hazardous Substances Data: 108579-54-0(Hazardous Substances Data)

Upstream product

• 38225-20-6 α-(trimethylsilyl)benzylthiol 

Downstream Products

• 106697-85-2 (Bromo-trimethylsilanyl-trimethylsilanylmethylsulfanyl-methyl)-benzene 
• 106697-96-5 (2S,3R,4R)-2-Phenyl-2-trimethylsilanyl-tetrahydro-thiophene-3,4-dicarboxylic acid dimethyl ester 
• 106697-92-1 (2R,3R)-2-Phenyl-2-trimethylsilanyl-tetrahydro-thiophene-3-carboxylic acid methyl ester 
• 106697-94-3 (2S,3S)-2-Phenyl-2-trimethylsilanyl-tetrahydro-thiophene-3-carbonitrile 
• 108579-50-6 (3S,4S)-2-Phenyl-tetrahydro-thiophene-3,4-dicarboxylic acid diethyl ester 
• 108579-48-2 (Trimethylsilanyl-trimethylsilanylmethanesulfinyl-methyl)-benzene 

Relevant articles and documents

Thiocarbonyl Ylides. VI. New Generation of Thiocarbonyl Ylides from Organosilicon Compounds Containing Sulfur and Their 1,3-Cycloadditions

Thermolysis of bromo(trimethylsilyl)methyltrimethylsilylmethyl sulfide was found to give a thiocarbonyl ylide, the 1,3-cycloaddition of which proved a new method for the synthesis of tetrahydrothiophenes.The effect of the silyl group of the ylide on the regio- and stereoselectivity in these 1,3-dipolar cycloaddtions is discussed.Keywords---thiocarbonyl ylide; 1,3-cycloaddition; organosilicon compound; thermolysis; tetrahydrothiophene; regioselectivity