108587-11-7Relevant academic research and scientific papers
SOLVOLYTIC HYDROPEROXIDE REARRANGEMENTS III. STEREOSELECTIVE REARRANGEMENTS OF METHYLATED CYCLOPROPYL CARBINOLS.
Ronald, Robert C.,Lillie, Thomas S.
, p. 5787 - 5790 (1986)
Solvolysis of 1-methylspirooctan-4-ols, 1-3, in acidified THF-90percent H2O2 through a combination of cyclopropylcarbinyl and Criegee rearrangements constitutes a new stereoselective synthesis of 3-alkyl-4-hydroxycyclooctanones.
A Novel Thermal Rearrangement of Allylic Nitro Derivatives into Allylic Alcohols
Boivin, Jean,Kaim, Laurent El,Kervagoret, Jocelyne,Zard, Samir Z.
, p. 1006 - 1008 (2007/10/02)
Heating secondary and tertiary allylic nitro compounds gives the corresponding rearranged allylic alcohols in moderate to good yield.
