108593-10-8Relevant academic research and scientific papers
Dithio- and Thionoesters, 63 [1] Bis(alkylthio)stilbenes by Reductive Dimerisation of Aryldithiocarboxylic Acid Esters
Hartke, Klaus,Bien, Notker,Weller, Frank
, p. 1173 - 1182 (2007/10/03)
Reaction of o- and p-alkyl substituted dithiobenzoic esters 5 with LDA and methyl iodide lead to the formation of the 1,2-bis(methylthio)stilbenes 9/10 and 16 by reductive dimerisation. The p-methyl dithiobenzoic ester 15b, however, suffers a Claisen condensation with lithium hexamethyldisalazane to yield the stilbene derivative 17. Even the o-methyldithiobenzoic acid 19 is reductively dimerized by LDA giving after methylation a mixture of the stilbenes 9a/10a and 20.
Electroreduction of Organic Compounds, 9. - Convenient Electrochemical Preparation of Thioacetals from Dithioesters
Drosten, Gisela,Mischke, Peter,Voss, Juergen
, p. 1757 - 1762 (2007/10/02)
Thioacetals are obtained as main products on electroreduction of alkyl dithiocarboxylates of various types in the presence of dimethyl sulfate in methanol. (Z)- and (E)-1,2-diaryl-1,2-bis(methylthio)ethenes are formed as byproducts.No reduction to form be
