108636-25-5Relevant articles and documents
Facile synthesis of bicyclo orthoesters and bicyclo amide acetals using α,α-difluoroalkylamines
Tange, Seiko,Fukuhara, Tsuyoshi,Hara, Shoji
experimental part, p. 3219 - 3222 (2009/05/07)
Bicyclo orthoesters and amide acetals were prepared from the corresponding triols or diethanolamines using α,α-difluoroalkylamines. The reaction proceeded under milder conditions than conventional methods. 4-tert-Butyl-1-(4-ethynylphenyl)trioxabicyclo[2.2.2]octane, a new class of insecticide, was prepared from a triol in three steps using a difluoroalkylamine.