108639-47-0Relevant academic research and scientific papers
A 3-hydroxychromone with dramatically improved fluorescence properties
Klymchenko, Andrey S.,Ozturk, Turan,Pivovarenko, Vasyl G.,Demchenko, Alexander P.
, p. 7967 - 7970 (2001)
A new 3-hydroxychromone derivative, 2-(6-diethylaminobenzo[b]furan-2-yl)-3-hydroxychromone, has been synthesized by a concise route. Possessing dual emission common for 3-hydroxyflavones, it exhibits strong red shifts of both absorption and fluorescence spectra, which makes it the longest wavelength fluorescent dye among all known chromones. It also demonstrates a significant increase in fluorescence quantum yield in aprotic solvents and shift in solvent-polarity-dependent switch between normal and tautomer emissive forms. This derivative offers new possibilities in designing novel molecular sensors.
Modulation of the solvent-dependent dual emission in 3-hydroxychromones by substituents
Klymchenko, Andrey S.,Pivovarenko, Vasyl G.,Ozturk, Turan,Demchenko, Alexander P.
, p. 1336 - 1343 (2003)
3-Hydroxychromones (3HCs) are fluorescent dyes, which respond to solvent perturbations by shifts and changes in the relative intensity of the two well-separated bands in the emission spectra. These bands originate from an excited state intramolecular prot
A Novel Synthesis of Benzofuran and Related Compounds. III. The Vilsmeier Reaction of Phenoxyacetaldehyde Diethyl Acetals
Hirota, Takashi,Fujita, Hiroko,Sasaki, Kenji,Namba, Tetsuto
, p. 1715 - 1716 (2007/10/02)
A novel synthesis of 2-benzofurancarbaldehydes by the Vilsmeier reaction of phenoxyacetaldehyde diethyl acetals is described.
