1086432-03-2Relevant academic research and scientific papers
C1-symmetric monosubstituted chiral diene ligands in asymmetric rhodium-catalyzed 1,4-addition reactions
Gendrineau, Thomas,Chuzel, Olivier,Eijsberg, Hendrik,Genet, Jean-Pierre,Darses, Sylvain
supporting information; experimental part, p. 7669 - 7672 (2009/04/10)
One trumps two: Monosubstituted chiral bicyclo[2.2.2]octadiene ligands, derived from carvone, form complexes with rhodium to catalyze the asymmetric addition of boronic acid substrates to α,β-unsaturated ketones (see scheme). The 1,4-adducts are produced
