108661-41-2Relevant academic research and scientific papers
N-CARBODIIMIDES. ISOMERIC TRANSFORMATIONS AND REACTIONS WITH PROTON-CONTAINING NUCLEOPHILIC REAGENTS
Vovk, M. V.,Dorokhov, V. I.,Samarai, L. I.
, p. 654 - 658 (2007/10/02)
The conditions for the isomerization of N-carbodiimides to N-alkylidene-N'-acylureas were investigated.In the reaction of N-carbodiimides with alcohols, phenols, thiophenols, and imines fragmentation of the carbodiimides occurs with the formation of 1-alkoxy-, 1-aryloxy-, 1-arylthio-, and 1-alkylideneaminoalkyl isocyanates and amides.The products from the reaction with water and with tert-butylamine are the amide, ketone, and N-alkylimine.
