108671-47-2Relevant articles and documents
Facile Diastereoseparation of Glycosyl Sulfoxides by Chiral Stationary Phase
Taniguchi, Tohru,Asahata, Mai,Nasu, Akihito,Shichibu, Yukatsu,Konishi, Katsuaki,Monde, Kenji
, p. 534 - 539 (2016)
Separation of the diastereomers of glycosyl sulfoxides differing in the sulfur chirality has been difficult. This article presents a fast and scalable method for their diastereoseparation using a chiral stationary phase. The usefulness of this method was
A synthesis of 1-lithiated glycals and 1-tributylstannyl glycals from 1-phenylsulfinyl glycals via sulfoxide-lithium ligand exchange
Jarowicki, Krzysztof,Kilner, Colin,Kocienski, Philip J.,Komsta, Zofia,Milne, Jacqueline E.,Wojtasiewicz, Anna,Coombs, Victoria
experimental part, p. 2747 - 2763 (2009/04/07)
1-Lithiated glycals generated by reaction of 1-phenyl-sulfinyl glycals with either t-BuLi or PhLi are transformed to 1-tributylstannyl glycals on reaction with tributyltin chloride. Georg Thieme Verlag Stuttgart.