108734-00-5Relevant academic research and scientific papers
One-Pot Preparation of α-Cyanovinyl Ethers (2-Alkoxy-2-alkenenitriles) from Vinyl Ethers: Elaboration to 3-Alkoxy-2-oxo-3-alkenenitriles and Aluminium Chloride-Catalyzed Cycloadditions to Cyclopentadiene
Hoffmann, H. M. R.,Giesel, Kunibert,Lies, Reinhard,Ismail, Zeinhom M.
, p. 548 - 551 (2007/10/02)
A variety of α-cyanovinyl ethers have been prepared by 3 different routes and elaborated to 3-alkoxy-2-oxo-3-alkenenitriles.The latter, in the presence of cyclopentadiene and aluminium chloride, give novel bridged 7-membered cycloadducts with loss of hydrogen cyanide.
