1087349-82-3

Basic information

• Product Name: (R)-3-but-3-enyl-cyclohexanone
• Synonyms: (R)-3-but-3-enyl-cyclohexanone
• CAS NO: 1087349-82-3
• Molecular Weight: 152.236
• Mol File: 1087349-82-3.mol

Chemical Properties

• CAS DataBase Reference: (R)-3-but-3-enyl-cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-3-but-3-enyl-cyclohexanone(1087349-82-3)
• EPA Substance Registry System: (R)-3-but-3-enyl-cyclohexanone(1087349-82-3)

Safety Data

• Hazardous Substances Data: 1087349-82-3(Hazardous Substances Data)

Upstream product

• 930-68-7 cyclohexenone 
• 7103-09-5 4-but-1-enylmagnesium bromide 

Relevant articles and documents

Enantioselective Cu-catalyzed 1,4-addition of Grignard reagents to cyclohexenone using Taddol-derived phosphine-phosphite ligands and 2-methyl-THF as a solvent

A small library of modular P,P ligands was screened and a potent Cu-based catalyst system was identified for highly enantioselective 1,4-additions to cyclohexenone with an unprecedented broad spectrum of Grignard reagents. Surprisingly, the highest selectivities were achieved in most cases in 2-methyl-THF, a green solvent underestimated so far.