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BENZENEPEROXYSELENINIC ACIDS - SYNTHESIS AND PROPERTIES
Syper, Ludwik,Mlochowski, Jacek
, p. 207 - 214 (2007/10/02)
Benzeneperoxyseleninic acid (3) and its analogs, 2-nitro and 2,4-dinitrobenzeneperoxyseleninic acids (10, 11), were obtained by oxidation of corresponding arylseleninic acids or diaryldiselenides with hydrogen peroxide.Their chemical properties were studied and rearrangement of 3 to benzeneselenic acid 7 was found as an useful method for preparation of this compound.It was also shown that peroxyseleninic acid 10 can be used as an efficient oxidant in the Baeyer-Villiger transformation of the formyl group into formyloxy one.
