108787-95-7Relevant academic research and scientific papers
BENZENEPEROXYSELENINIC ACIDS - SYNTHESIS AND PROPERTIES
Syper, Ludwik,Mlochowski, Jacek
, p. 207 - 214 (1987)
Benzeneperoxyseleninic acid (3) and its analogs, 2-nitro and 2,4-dinitrobenzeneperoxyseleninic acids (10, 11), were obtained by oxidation of corresponding arylseleninic acids or diaryldiselenides with hydrogen peroxide.Their chemical properties were studied and rearrangement of 3 to benzeneselenic acid 7 was found as an useful method for preparation of this compound.It was also shown that peroxyseleninic acid 10 can be used as an efficient oxidant in the Baeyer-Villiger transformation of the formyl group into formyloxy one.
The Baeyer-Villiger Oxidation of Aromatic Aldehydes and Ketones with Hydrogen Peroxide Catalyzed by Selenium Compounds
Syper, Ludwik
, p. 167 - 172 (2007/10/02)
A series of organoselenium compounds was investigated as activators of hydrogen peroxide in the Baeyer-Villiger oxidation.As a result, a convenient and cheap method for transformation of aromatic aldehydes, having polycondensed ring systems or electron-donating substituents, and polymethoxy derivatives of acetophenone, into phenols was elaborated.This method utilizes hydrogen peroxide activated by areneseleninic acids, as oxidizing agent.
