108794-37-2

Basic information

• Product Name: 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-D-galactopyranoside
• CAS NO: 108794-37-2
• Molecular Weight: 308.261
• Mol File: 108794-37-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-D-galactopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-D-galactopyranoside(108794-37-2)
• EPA Substance Registry System: 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-D-galactopyranoside(108794-37-2)

Safety Data

• Hazardous Substances Data: 108794-37-2(Hazardous Substances Data)

Upstream product

• 22331-11-9 2,3-di-O-acetyl-1,6-anhydro-β-D-glucose 
• 34245-85-7 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-glucopyranosyl bromide 
• 93253-40-8 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-galactopyranosyl bromide 
• 108-24-7 acetic anhydride 
• 4098-06-0 triacetyl-D-galactal 

Downstream Products

• 141395-48-4 1,3,4,6-tetra-O-acetyl-2-deoxy-2-fluoro-α/β-D-glucopyranoside 
• 357979-11-4 2-deoxy-2-fluoro-3,4,6-tri-O-acetyl-α-D-glucopyranosyl 1-diphenylphosphate 
• 1012308-39-2 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-β-D-glucopyranosyl 4-{4-[bis(2-chloroethyl)amino]phenyl}butyrate 
• 86783-82-6 2-fluoro-D-glucose 
• 111524-65-3 2',4'-Dinitrophenyl 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-β-D-glucopyranoside 
• 111524-64-2 2',4'-Dinitrophenyl 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-glucopyranoside 
• 1274877-62-1 2,3,4,6-tetra-O-benzyl-1-deoxy-α-D-galacto-hept-2-ulopyranosyl-(2-1)-3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-β-D-glucopyranoside 
• 1274877-58-5 2,3,4,6-tetra-O-benzyl-1-deoxy-α-D-galacto-hept-2-ulopyranosyl-(2-1)-3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-glucopyranoside 
• 1313741-13-7 C₄₁H₄₇FO₁₀ 

Relevant articles and documents

Design and synthesis of 2'-deoxy-2'-fluorodisaccharides as mechanism- based glycosidase inhibitors that exploit aglycon specificity

Stable, aglycon-specific inactivators of glycosidases have considerable potential as tools in the study of mechanisms of oligosaccharide processing, and possibly as avenues toward new therapeutics. Glycosidases for which the rate-determining step with the

2'-FLUOROMALTOSE: SYNTHESIS AND PROPERTIES OF 4-O-(2-DEOXY-2-FLUORO-α-D-GLUCOPYRANOSYL)-D-GLUCOPYRANOSE, AND THE CRYSTAL STRUCTURE OF 2,3-DI-O-ACETYL-1,6-ANHYDRO-4-O-(3,4-TRI-O-ACETYL-2-DEOXY-2-FLUORO-α-D-GLUCOPYRANOSYL)-β-D-GLUCOPYRANOSE

Coupling of 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-glucopyranosyl bromide and 3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-galactopyranosyl bromide with 2,3-di-O-acetyl-1,6-anhydro-β-D-glucose, under Koenigs-Knorr reaction conditions gave, in both instances, only the corresponding α-(1->4)-linked disaccharides.In the first case, the linkage was verified by 1H- and 19F-n. m. r., and by X-ray crystallographic analysis of 2,3-di-O-acetyl-1,6-anhydro-4-O-(3,4,6-tri-O-acetyl-2-deoxy-2-fluoro-α-D-glucopyranosyl)-β-D-glucopyranose.Deprotection of this disaccharide gave 2'-deoxy-2'-fluoromaltose.Maltose and its fluorinated analogue displayed similar 1H- and 13C-n. m. r. spectra and optical rotations, indicating that these two sugars are isomorphous in solution and suggesting that 2'-deoxy-2'-fluoromaltose might be a suitable substrate for studies of α-glycosidases.