108860-00-0

Basic information

• Product Name: (S)-tert-butyl 4-<(benzyloxycarbonyl)amino>-3-oxo-6-methylheptanoate
• Synonyms: (S)-tert-butyl 4-<(benzyloxycarbonyl)amino>-3-oxo-6-methylheptanoate
• CAS NO: 108860-00-0
• Molecular Weight: 363.454
• Mol File: 108860-00-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (S)-tert-butyl 4-<(benzyloxycarbonyl)amino>-3-oxo-6-methylheptanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-tert-butyl 4-<(benzyloxycarbonyl)amino>-3-oxo-6-methylheptanoate(108860-00-0)
• EPA Substance Registry System: (S)-tert-butyl 4-<(benzyloxycarbonyl)amino>-3-oxo-6-methylheptanoate(108860-00-0)

Safety Data

• Hazardous Substances Data: 108860-00-0(Hazardous Substances Data)

Upstream product

• 540-88-5 acetic acid tert-butyl ester 
• 51021-87-5 N-benzyloxycarbonyl-L-leucine methyl ester 
• 2018-66-8 Z-Leu-OH 
• 1207973-75-8 lithium tert-butyl acetate 
• 109075-73-2 benzyl (S)-[1-(N-methoxy-N-methylamino)-4-methyl-1-oxopentan-2-yl]carbamate 

Downstream Products

• 108860-06-6 (3S,4S)-4-Benzyloxycarbonylamino-3-hydroxy-6-methyl-heptanoic acid tert-butyl ester 
• 108860-07-7 (3R,4S)-4-Benzyloxycarbonylamino-3-hydroxy-6-methyl-heptanoic acid tert-butyl ester 

Relevant articles and documents

An efficient synthesis of γ-amino β-ketoester by cross-Claisen condensation with α-amino acid derivatives

Cross-ester condensation between N-protected amino acid ester and the lithium enolate prepared from alkyl acetate gave the corresponding β-ketoester in high yield without the formation of the tertiary alcohol that is commonly seen as by-product. This inte

Synthesis and Reduction of α-Amino Ketones Derived from Leucine

New α-amino ketones (5) derived from leucine have been synthesized by reaction of organometallics on N-methoxy-N-methylamide (4).The stereoselectivity of reduction of the α-amino ketones (5) was studied.The stereochemistry of the resulting α-amino alcohol