108866-54-2Relevant academic research and scientific papers
Noncovalent secondary interactions in Co(II)salen complexes: O2 binding and catalytic activity in cyclohexene oxygenation
Fiammengo, Roberto,Bruinink, Christiaan M.,Crego-Calama, Mercedes,Reinhoudt, David N.
, p. 8552 - 8557 (2007/10/03)
The O2 affinity of Co(II)Salen complexes 1-4 and their reactivity in cyclohexene oxygenation reactions of Co(II)Salen complexes 1-4 are modulated by noncovalent interactions such as hydrogen bonding and steric hindrance using a functionalized diamino bridge. Higher O2 affinity is observed in the case of efficient hydrogen-bonding interactions (complex 1), while increased steric hindrance (cis vs trans diamino bridge) around the Co-coordinated O2 is influencing the reactivity of the complexes.
Stereocontrolled Syntheses for the Six Diastereomeric 1,2-Dihydroxy-4,5-diaminocyclohexanes: PtII Complexes and P-388 Antitumor Properties
Witiak, Donald T.,Rotella, David P.,Filppi, Joyce A.,Gallucci, Judith
, p. 1327 - 1336 (2007/10/02)
Stereocontrolled syntheses for the six diastereomeric 1,2-dihydroxy-4,5-diaminocyclohexanes 3a-f from cyclohexene diamines cis-4 and trans-5 are described.Cbz-protected species cis-9 and trans-11, respectively, served as a source of stable Cbz-protected p
