108886-75-5Relevant academic research and scientific papers
7,7-Dimethyltricyclo2,8>octan-3-ones as Synthetic Intermediates. II. A Total Synthesis of (+-)-Pentalene, an Angular Triquinane Sesquiterpene
Imanishi, Takeshi,Yamashita, Masayuki,Ninbari, Fusako,Tanaka, Tetsuaki,Iwata, Chuzo
, p. 1371 - 1378 (2007/10/02)
A total synthesis of (+-)-pentalenene (3), one of the least-oxidized triquinane sesquiterpenes, is described.By a several-step sequence, 4,4-dimethyl-2-cyclopentenone (5) was derived to a tricyclooctanone (4), which was subjected to a reductive C2-C8 bond
