108906-56-5

Upstream product

• 500102-44-3 (4R,4aS,6S,7S,7aS)-7-Benzyloxymethyl-4-methyl-6-((2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-hexahydro-cyclopenta[c]pyran-3-one 
• 74808-09-6 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate 
• 500102-43-2 (4R,4aS,6S,7S,7aS)-7-Benzyloxymethyl-6-hydroxy-4-methyl-hexahydro-cyclopenta[c]pyran-3-one 
• 500102-35-2 (2S,3S)-2-((E)-Buta-1,3-dienyl)-5-triisopropylsilanyloxy-pentane-1,3-diol 
• 500102-38-5 (E)-4-[(4S,5S)-5-((E)-Buta-1,3-dienyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-but-2-enoic acid methyl ester 
• 500102-36-3 {2-[(4S,5S)-5-((E)-Buta-1,3-dienyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-ethoxy}-triisopropyl-silane 
• 500102-45-4 (4R,4aS,6S,7S,7aS)-7-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-4-methyl-hexahydro-cyclopenta[c]pyran-3-one 
• 500102-39-6 1-[(E)-(1S,2S)-1-((E)-4-Benzyloxy-but-2-enyl)-2-benzyloxymethyl-hexa-3,5-dienyloxymethyl]-4-methoxy-benzene 
• 500102-40-9 2-[(1R,2R,3S,4S)-3-Benzyloxymethyl-4-(4-methoxy-benzyloxy)-2-((Z)-propenyl)-cyclopentylmethyl]-[1,3]dioxolane 
• 500102-41-0 [(1S,2S,3S,5R)-2-Benzyloxymethyl-5-[1,3]dioxolan-2-ylmethyl-3-(4-methoxy-benzyloxy)-cyclopentyl]-methanol 
• 500102-42-1 (4aR,6S,7S,7aS)-7-Benzyloxymethyl-6-(4-methoxy-benzyloxy)-hexahydro-cyclopenta[c]pyran-3-one 
• 500102-37-4 [(4S,5S)-5-((E)-Buta-1,3-dienyl)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-acetaldehyde 

Relevant academic research and scientific papers

Iron-catalyzed enediene carbocyclizations. The total synthesis of (-)-gibboside

The first total synthesis of (-)-gibboside is reported. The route features a novel iron-catalyzed carbocyclization as the key step for the construction of the cis,trans,cis-tetrasubstituted cyclopentane core.