109050-49-9Relevant articles and documents
VERSCHIEDENE STRUKTUREN VON β-DIKETONDERIVATEN DES QUECKSILBERS
Depmeier, Wulf,Dietrich, Klaus,Koenig, Klaus,Musso, Hans,Weiss, Willy
, p. C1 - C4 (1986)
In β-diketones the mercuric ion is bound to carbon atoms even if the central carbon atom is hindered by bulky groups (e.g. i-propyl, t-butyl) or if one oxygen is replaced by nitrogen.In the case of a sulfur atom replacing an oxygen, however, the ligands come into contact with the Hg(2+) at the sulfur atoms; this shown by X-ray crystal structure analysis.
Organic Metal Complexes, XIX. - The Structure of the Compounds from Mercury(II) and Substituted β-Diketones
Koenig, Klaus,Weiss, Willy,Musso, Hans
, p. 1271 - 1276 (2007/10/02)
3-Methyl-, 3-ethyl-, and 3-phenylacetylacetone (6a-c) react with mercury(II) at C-3 to give 2:1 compounds of type 8, whereas 3-isopropyl- and 3-tert-butylacetylacetone and also 1,8-dekalinedione (15a) from polymer 1:1 complexes, in which the ligands are c
