109053-72-7

Upstream product

• 768-33-2 phenyldimethylsilyl chloride 

Downstream Products

• 109053-79-4 (Z)-(S)-1-((1S,5R,7R)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3-(dimethyl-phenyl-silanyl)-hex-4-en-1-one 
• 109120-50-5 (2S,3S)-3-(Dimethyl-phenyl-silanyl)-2-methyl-3-phenyl-propionic acid methyl ester 
• 109053-85-2 methyl 3-(dimethyl(phenyl)silyl)-3-phenylpropanoate 
• 109053-84-1 (R)-3-(Dimethyl-phenyl-silanyl)-heptanoic acid methyl ester 
• 164203-14-9 (3S)-3-dimethyl(phenyl)silyl-3-phenylpropanoic acid 
• 109120-49-2 (S)-1-((1S,5R,7R)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3-(dimethyl-phenyl-silanyl)-3-phenyl-propan-1-one 
• 109120-45-8 (S)-1-((1S,5R,7R)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3-(dimethyl-phenyl-silanyl)-butan-1-one 

Relevant academic research and scientific papers

Preparation of Enantiomerically Pure β-Silylcarboxyl Derivatives by Asymmetric 1,4-Addition to N-Enoyl-sultams

EtAlCl2-promoted additions of organocopper reagents to camphor-derived, conjugated N-enoyl-sultams gave saturated and olefinic β-silylcarboxyl derivatives with high diastereodifferentiation.Nondestructive removal of the chiral auxiliary followed by oxidative Si-C bond cleavage furnished enantiomerically pure acetate-derived aldols and propionate-derived 'anti'-aldols (via silyl-directed α-methylation).