109055-08-5

Basic information

• Product Name: 4-O-acetyl-1,6-anhydro-2,3-O-endo-benzylidene-β-D-mannopyranose
• Synonyms: 4-O-acetyl-1,6-anhydro-2,3-O-endo-benzylidene-β-D-mannopyranose
• CAS NO: 109055-08-5
• Molecular Weight: 292.288
• Mol File: 109055-08-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-O-acetyl-1,6-anhydro-2,3-O-endo-benzylidene-β-D-mannopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 4-O-acetyl-1,6-anhydro-2,3-O-endo-benzylidene-β-D-mannopyranose(109055-08-5)
• EPA Substance Registry System: 4-O-acetyl-1,6-anhydro-2,3-O-endo-benzylidene-β-D-mannopyranose(109055-08-5)

Safety Data

• Hazardous Substances Data: 109055-08-5(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 71049-45-1 1,6-anhydro-2,3-O-endo-benzylidene-β-D-mannopyranose 

Downstream Products

• 67313-49-9 4-O-acetyl-1,6-anhydro-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranose 
• 55682-57-0 1,6-anhydro-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranose 
• 157612-18-5 4-O-acetyl-1,6-anhydro-3-O-benzyl-β-D-mannopyranose 

Relevant articles and documents

Facile Preparation of 1,6-Anhydro-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranose and Its 4-O-Substituted Derivatives

Treatment of 1,6-anhydro-2,3-O-endo-benzylidene-β-D-mannopyranose derivatives with trimethylamine-borane (1/1)-aluminium chloride resulted in highly regioselective fission of the cyclic acetals to give the corresponding 2-O-unprotected-3-O-benzyl derivatives. Trifluoromethane-sulfonylation of these, followed by nucleophilic substitution, afforded 2-azido-2-deoxy derivatives in good yields.