109057-52-5Relevant academic research and scientific papers
Acylation of diselenides and disulfides with N-acylbenzotriazoles promoted by SmI2
Tu, Ya Wei,Zhou, Lie Jin,Lv, Xin,Wang, Xiao Xia
, p. 435 - 439 (2014/05/06)
The acylation of diselenides or disulfides with N-acylbenzotriazoles mediated by SmI2 has been achieved successfully without the presence of HMPA, and the corresponding selenolesters or thioesters have been prepared in good yields.
Investigation on the se-acylation with N-acylbenzotriazoles
Jiang, Junyan,Wang, Wencun,Wang, Xiaoxia,Zhu, Xiangming,Li, Zhifang
experimental part, p. 2047 - 2054 (2011/12/01)
The acylation of Se-nucleophiles with N-acylbenzotriazoles was investigated. Samarium phenylselenolate and benzylselenolate (RSeSmI 2) reacted with N-aroyl and N-alkanoylbenzotriazoles smoothly and afforded the corresponding selenol esters in g
Palladium-catalyzed selenoacylation of allenes leading to the regioselective formation of functionalized allyl selenides
Toyofuku, Masashi,Murase, Erika,Fujiwara, Shin-ichi,Shin-ike, Tsutomu,Kuniyasu, Hitoshi,Kambe, Nobuaki
supporting information; experimental part, p. 3957 - 3960 (2009/05/30)
(Chemical Equation Presented) Palladium-catalyzed regio- and stereoselective selenoacylation of allenes with selenol esters proceeded to produce functionalized allyl selenides with the acyl moiety at the inner carbon and the SePh group at the terminal car
A one-pot conversion of carboxylic acids into homoallylic alcohols
Ollivier,Panchaud,Renaud
, p. 1573 - 1578 (2007/10/03)
A one-pot procedure for the conversion of carboxylic acids into homoallylic alcohols under remarkably mild and selective conditions is described. The triethylammonium salts of alkanoic acids are treated with Bu3P/PhSeCl to afford the correspond
A regioselective Aluminium Chloride-catalyzed Acylation of Allylic Selenides via α-Silyl Intermediates
Hiroi, Kunio,Sato, Hiroyasu
, p. 1723 - 1726 (2007/10/02)
The aluminium chloride-catalyzed acylation of α-silylallylic selenides with acid chlorides at -78 deg C produced γ-acylated vinylic selenides regioselectively. α-Silylallylic selenides in some cases underwent shifts of the selenenyl groups by the catalysis with aluminium chloride, affording γ-silylallylic selenides.This regioselective acylation of allylic selenides provides a new route to dihydrojasmone.
