1091627-47-2Relevant academic research and scientific papers
Remarkable effects of chirality on deslipping reactions of diastereomeric rotaxanes and relevant mechanism involving pre-equilibrium
Hirose, Keiji,Nakamura, Yamato,Tobe, Yoshito
supporting information; experimental part, p. 145 - 147 (2009/08/07)
The first clear differentiation on deslipping rates affected by the difference in the diastereomeric stereocenters of rotaxanes up to 8.4 times and unexpectedly large steric kinetic isotope effect on the deslipping reaction.
