1092491-50-3Relevant academic research and scientific papers
Nickel-catalyzed asymmetric intramolecular reductive heck reaction of unactivated alkenes
Yang, Feiyan,Jin, Youxiang,Wang, Chuan
supporting information, p. 6989 - 6994 (2019/09/30)
An asymmetric Ni-catalyzed intramolecular reductive Heck reaction of unactivated alkenes tethered to aryl bromides has been accomplished, providing a variety of benzene-fused cyclic compounds bearing a quaternary stereogenic center in good to excellent yi
Palladium-mediated highly regio- and stereoselective intermolecular β-arylation on allylic alcohols: Synthesis of functionalized allylic alcohols
Krishna,Reddy, A. Gopi Krishna,Ramulu, B. Venkat,Mahendar,Satyanarayana
supporting information; experimental part, p. 375 - 380 (2012/03/11)
An efficient and highly regio- and stereoselctive Pd-catalyzed β-arylation method for the formation of β-aryl allylic alcohols, employing aryl iodides, 1-bromo-2-iodobenzenes, and 2-bromobezaldehydes as coupling partners, is presented. The β-aryl allylic
Asymmetric palladium-catalyzed intramolecular α-arylation of aldehydes
Garcia-Fortanet, Jorge,Buchwald, Stephen L.
supporting information; experimental part, p. 8108 - 8111 (2009/04/13)
(Chemical Equation Presented) Phoxy ligand: The first catalytic method for the asymmetric palladium-catalyzed intramolecular α-arylation of α-branched aldehydes was developed (see scheme). This process is distinguished by the high yields and enantioselectivities that can be obtained, making this protocol a useful synthetic tool for further applications.
