1092730-02-3Relevant articles and documents
Green synthesis of tertiary alkylselanylphosphine chalcogenides via catalyst-and solvent-free addition of secondary phosphine chalcogenides to vinyl selenides
Gusarova,Chernysheva,Yas'Ko,Trofimov
, p. 526 - 534 (2015)
Secondary phosphine sulfides and phosphine selenides react with vinyl selenides under mild conditions (80-82°C, without catalyst and solvent) to form regioselectively functionalized anti-Markovnikov adducts in high yield.
Radical addition of secondary phosphine sulfides and selenides to vinyl selenides
Gusarova, Nina K.,Chernysheva, Nataliya A.,Yas'ko, Svetlana V.,Kazantseva, Tatyana I.,Ushakov, Igor A.,Trofimov, Boris A.
experimental part, p. 2743 - 2746 (2009/04/04)
The first examples of a facile hydrochalcogenophosphorylation of alkyl vinyl selenides are reported. The regiospecific addition of secondary phosphine sulfides and phosphine selenides to vinyl selenides proceeds under radical initiation (AIBN, 65-70°C, 1 h or UV-irradiation, 1 h) to afford the anti-Markovnikov adducts in 87-95% yield. Georg Thieme Verlag Stuttgart.
