109279-05-2

Basic information

• Product Name: (2S,3S)-(+)-2,3-dicarbomethoxy spirocyclopropane-1,9'-fluorene
• CAS NO: 109279-05-2
• Molecular Weight: 308.334
• Mol File: 109279-05-2.mol

Chemical Properties

• CAS DataBase Reference: (2S,3S)-(+)-2,3-dicarbomethoxy spirocyclopropane-1,9'-fluorene(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-(+)-2,3-dicarbomethoxy spirocyclopropane-1,9'-fluorene(109279-05-2)
• EPA Substance Registry System: (2S,3S)-(+)-2,3-dicarbomethoxy spirocyclopropane-1,9'-fluorene(109279-05-2)

Safety Data

• Hazardous Substances Data: 109279-05-2(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 109297-12-3 C₄₉H₅₆O₄ 

Downstream Products

• 109172-65-8 C₃₁H₂₄ 
• 109172-65-8 C₃₁H₂₄ 
• 109279-06-3 C₃₁H₂₄ 

Relevant articles and documents

Asymmetric Induction in 1,3-Dipolar Cycloaddition of Diazofluorene with Menthyl or 8-Phenylmenthyl Acrylate and Fumarate Derivatives

Optical yields in the 1,3-dipolar cycloaddition of diazofluorene with chiral acrylate or fumarate derivatives were found to be considerably improved by use of Corey's 8-phenylmenthyl group as a chiral O-alkyl group in these esters.The absolute stereochemistry of resulting cyclopropanes is different from the one expected from the "diazo-exchange" mechanism proposed by Walborsky et al.

Asymmetric Transformation in Photoequilibrium Systems: Diastereoselective Isomerization of N-(R)-(+)-α-Arylethylfluorene-9-spiro-1'-cyclopropane-2'-carboxamide Derivatives

Photochemically induced asymmetric transformation in the isomerizations of N-(R)-(+)-α-arylethylfluorene-9-spiro-1'-cyclopropane-2'-carboxamide derivatives showed moderate to high diastereoselectivity.