109297-28-1Relevant articles and documents
Ruthenium-catalyzed intramolecular selective halogenation of O-methylbenzohydroximoyl halides: A new route to halogenated aromatic nitriles
Chinnagolla, Ravi Kiran,Pimparkar, Sandeep,Jeganmohan, Masilamani
supporting information, p. 3146 - 3148 (2013/06/04)
The intramolecular halogenation of O-methylbenzohydroximoyl halides in the presence of a Ru catalyst and the ligand diphenylacetylene afforded halo substituted aromatic nitriles in a highly regioselective manner. Further, substituted nitriles were converted into substituted tetrazole derivatives in the presence of NaN3 and I2.
Reactions of Organic Anions. Part 180. Orientation of the Carbanion Attack of Chloromethyl p-Tolyl Sulphone on 1-Cyanonaphthalene Derivatives
Makosza, Mieczyslaw,Ostrowski, Stanislaw
, p. 1093 - 1097 (2007/10/02)
The carbanion of chloromethyl p-tolyl sulphone reacts with cyanonaphthalene derivatives to give bis-annulated products and/or SNAr products and/or products of nucleophilic substitution of hydrogen depending on the structure of the substrates and on reaction conditions.The orientation of the initial carbanion attack is discussed.