109322-33-0

Basic information

• Product Name: (+/-)-(Z)-cis-6,7-epoxy-3-nonen-2-one
• CAS NO: 109322-33-0
• Molecular Weight: 154.209
• Mol File: 109322-33-0.mol

Chemical Properties

• CAS DataBase Reference: (+/-)-(Z)-cis-6,7-epoxy-3-nonen-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(Z)-cis-6,7-epoxy-3-nonen-2-one(109322-33-0)
• EPA Substance Registry System: (+/-)-(Z)-cis-6,7-epoxy-3-nonen-2-one(109322-33-0)

Safety Data

• Hazardous Substances Data: 109322-33-0(Hazardous Substances Data)

Upstream product

• 109322-32-9 (+/-)-cis-6,7-epoxy-3-nonyn-2-one 
• 109322-32-9 5-((2S,3R)-3-Ethyl-oxiranyl)-pent-3-yn-2-one 

Downstream Products

• 88525-42-2 exo-3,4-dehydrobrevicomin 
• 62255-25-8 (+/-)-endo-Mus musculus pheromone 
• 62255-25-8 (2R,5S,7R)-exo-7-ethyl-5-methyl-6,8-dioxabicyclo[3.2.1]oct-3-ene 

Relevant articles and documents

APPLICATION OF THE CARBONYL EPOXIDE REARRANGEMENT TO THE FORMATION OF DIOXABICYCLOALKANES AND ALKENES. SYNTHESIS OF THE MUS MUSCULUS PHEROMONE

Acid-catalyzed intramolecular opening of epoxides by carbonyl groups provides a general stereocontrolled method for forming dioxabicyclo systems, including the (+/-)-Mus musculus pheromone and products corresponding to certain insect pheromones.

THE CARBONYL EPOXIDE REARRANGEMENT. A CHIRAL SYNTHESIS OF THE MUS MUSCULUS PHEROMONE

The carbonyl-epoxide rearrangement in conjunction with the Sharpless asymmetric epoxidation procedure has been applied to an efficient synthesis of both enantiomers corresponding to the Mus musculus pheromone.