109386-07-4

Upstream product

• 930-88-1 N-methylmaleimide 
• 109386-05-2 ((E)-2-Trimethylsilanyl-2-trimethylsilanylmethanesulfinyl-vinyl)-benzene 
• 109386-06-3 ((Z)-2-Trimethylsilanyl-2-trimethylsilanylmethanesulfinyl-vinyl)-benzene 
• 163589-71-7 ((E)-2-Trimethylsilanyl-2-trimethylsilanylmethanesulfinyl-vinyl)-benzene 
• 109386-03-0 α-(trimethylsilyl)stylyl (trimethylsilyl)methyl sulfide 
• 109386-04-1 (Z)-α-(trimethylsilyl)styryl trimethylsilylmethyl sulfide 
• 109386-03-0 (E)-α-(trimethylsilyl)styryl trimethylsilylmethyl sulfide 

Relevant academic research and scientific papers

NEW METHOD FOR GENERATION OF THIOCARBONYL YLIDES FROM BIS(TRIMETHYLSILYLMETHYL)SULFOXIDES AND THEIR APPLICATION TO CYCLOADDITIONS

Thiocarbonyl ylides were generated by heating of bis(trimethylsilylmethyl)sulfoxides.Cycloadditions of the ylides in the presence of dipolarophiles proceeded smoothly to give di- or tetrahydrothiophenes.

Generation of Thioketenes S-methylides and Their 1,3-Cycloadditions

Thioketene S-methylide was found to be generated by release of disiloxane from α-(trimethylsilyl) vinyl (trimethylsilyl)methyl sulfoxide and its 1,3-cycloaddition provided a novel method for synthesis of 2-alkylidenetetrahydrothiophenes.