109430-16-2Relevant academic research and scientific papers
Anomalous threo-Diastereoselectivity in Allylic Silane- or Stannane-Aldehyde Condensation Reactions: New Interpretation of the Antiperiplanar vs. Synclinal Problem on the Transition-state Conformations
Mikami, Koichi,Kawamoto, Kazuya,Loh, Teck-Peng,Nakai, Takeshi
, p. 1161 - 1163 (2007/10/02)
Unusual threo-diastereoselectivity has been observed in the intermolecular reactions of β-substituted crotyl-silane or -stannane with 2-benzyloxypropanal under chelation conditions, which implies preference for the synclinal over the antiperiplanar transition state.
