109459-29-2Relevant academic research and scientific papers
STUDIES ON THE REDUCTION OF CYCLIC 1,3-DIKETONES VIA THEIR TRIFLATES
Martinez, A. Garcia,Alvarez, R. Martinez,Casado, M. Madueno,Subramanian, L. R.,Hanack, M.
, p. 275 - 280 (1987)
Using 1,3-Cyclohexadione (1) and 5,5-dimethyl-1,3-Cyclohexadione (11) as examples, it is shown that 1,3-diketones can be transformed into monoketones, monoalcohols, alkanes and unsaturated ketones.
The regioselective trifluoromethylation of 1,3-bis(vinyl triflates) in the absence of external trifluoromethyl sources
Kawamoto, Takuji,Sasaki, Rio,Kamimura, Akio,Matsubara, Hiroshi
, p. 66 - 69 (2019)
We report the regioselective trifluoromethylation of 1,3-bis(vinyl triflates) via an allyl radical intermediate. In this reaction, the trifluoromethyl radical exclusively attacks the 4-position of the 1,3-diketone derivatives. The observed regioselectivit
VINYLFLUOROALKANE SULFONATE COMPOUND AND METHOD OF PRODUCING THE SAME
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Paragraph 0035, (2019/05/09)
PROBLEM TO BE SOLVED: To provide a technique of regioselectively introducing a fluoroalkyl group such as a trifluoromethyl group to an outer carbon of 1,3-diketone. SOLUTION: The present invention provides a method for producing a vinylfluoroalkane sulfon
