1094768-53-2Relevant academic research and scientific papers
Synthesis of C14,15-Dihydro-C22,25-epi north unit of cephalostatin 1 via "red-ox" modifications of hecogenin acetate
Lee, Seongmin,Jamieson, Daniel,Fuchs, Philip L.
supporting information; experimental part, p. 5 - 8 (2009/08/07)
The C14,15-Dihydro-C22,25-epi north unit of cephalostatin 1 has been synthesized in 11 operations from commercially available hecogenin acetate via multiple reductions and oxidations. The key transformations include (i) Cr VI-catalyzed E-ring o
