1094860-87-3Relevant academic research and scientific papers
Highly efficient substitution of allylic picolinates with copper reagents derived from aryl-, alkenyl-, furyl-, and thienyl-lithiums
Kiyotsuka, Yohei,Kobayashi, Yuichi
scheme or table, p. 676 - 684 (2010/09/05)
Substitution of optically active allylic picolinate, cis R1-CH(OC(O)(2-Py))CH{double bond, long}CHR2 (R1=(CH2)2Ph, R2=CH2OTBS), with phenylcopper reagents derived from salt free
New protocol for allylic substitution with aryl and alkenyl copper reagents derived from organolithiums
Kiyotsuka, Yohei,Kobayashi, Yuichi
scheme or table, p. 7256 - 7259 (2009/04/11)
Substitution of allylic picolinoates with copper reagents derived from sp2-carbon-lithiums and CuBr·Me2S was established to furnish anti SN2′ products with almost perfect regioselectivity and chirality transfer. The prepar
