109492-49-1Relevant articles and documents
Reactions of Ozonate and Superoxide Radical Anions
Forrester, Alexander R.,Purushotham, Vemishetti
, p. 211 - 218 (2007/10/02)
Potassium ozonate has been prepared by reaction of ozone with potassium superoxide dispersed in Freon-12.Orange solutions of potassium ozonate in benzene or toluene containing 18-crown-6 react with nitrone traps to give spin adducts mainly derived from the oxide radical anion, which is a decomposition product of the ozonate radical anion.With 2-methyl-2-nitrosopropane in toluene solution the ozonate gives five nitroxide radicals in whose formation the oxide radical anion is again implicated.With nitrosobenzene electron transfer occurs.Comparable reactions with superoxide are described.
