1095281-57-4

Downstream Products

• 1095281-62-1 (bis(2-diisopropylphosphino-4-tolyl)amide)Sc(NH[2,6-diisopropylphenyl])(C₆H₅) 
• 1095281-64-3 (bis(2-diisopropylphosphino-4-tolyl)amide)Sc(ND[2,6-diisopropylphenyl])(C₆D₅) 
• 1095281-60-9 [Sc(N[2-P(CHMe₂)2-4-methylphenyl]2)(CH₂C(CH₃)3)(NHC₆H₃-iPr₂-2,6)] 
• 1073683-79-0 (bis(2-diisopropylphosphino-4-tolyl)amide)Sc(NH[2,6-diisopropylphenyl])(CH₃) 
• 1095281-61-0 [Sc(N[2-P(CHMe₂)2-4-methylphenyl]2)(CH₂Si(CH₃)3)(NHC₆H₃-iPr₂-2,6)] 

Relevant academic research and scientific papers

Evidence for the existence of a terminal imidoscandium compound: Intermolecular C-H activation and complexation reactions with the transient Sc=NAr species

Don't blink or you'll miss it: A transient imidoscandium complex (see scheme) can be generated by several routes. The imido ligand can activate the C-H bond in pyridine and benzene, and it can be complexed with Al(CH 3)3 to yield an imide zwitterion. A combination of isotopic labeling, reactivity, and theoretical studies strongly endorse formation of a terminal imido ligand at scandium. (Chemical Equation Presented)