109564-84-3Relevant academic research and scientific papers
On the palladium(II)-catalysed oxidative rearrangement of propargylic acetates
Bartels,Mahrwald,Mueller
, p. 483 - 485 (2004)
The catalytic transformation of propargylic acetates into the corresponding α-acetoxyenones in the presence of palladium(II) chloride is described. Water is a necessary component in this unusual oxidative rearrangement.
Palladium-catalyzed [4 + 2] cycloaddition of aldimines and 1,4-dipolar equivalents via amphiphilic allylation
Hirata, Goki,Yamada, Naoshi,Sanada, Shohei,Onodera, Gen,Kimura, Masanari
, p. 600 - 603 (2015)
The combination of Pd catalyst and diethylzinc with triethylborane promotes the amphiphilic allylation of aldimines with 2,3-bismethylenebutane-1,4-diol derivatives to serve as bis-allylic zwitterion species to form 3,4-bismethylenepiperidines via a formal [4 + 2] cycloaddition reaction. 3,4-Bismethylenepiperidine rings are applicable for the synthesis of isoquinoline derivatives via the Diels-Alder reaction followed by an oxidation reaction with DDQ.
