1095650-32-0Relevant academic research and scientific papers
Copper-catalyzed highly enantioselective carbenoid insertion into Si-H bonds
Zhang, Yong-Zhen,Zhu, Shou-Fei,Wang, Li-Xin,Zhou, Qi-Lin
, p. 8496 - 8498 (2008)
(Chemical Equation Presented) Complete control: A highly efficient, copper-catalyzed, asymmetric carbenoid insertion into Si-H bonds, using chiral spiro diimine (SIDIM) ligands (see scheme, Ar=2,6-Cl2C 6H3, OTf=trifluoromethanesulfonate), produces a wide range of α-silylesters, in high yields with excellent enantiomeric excesses. This catalytic system offers unprecedented levels of enantiocontrol for the Si-H bond insertion reaction.
Chiral Dirhodium Tetraphosphate-Catalyzed Enantioselective Si-H Bond Insertion of α-Aryldiazoacetates
Cao, Jin,Yang, Liang-Liang,Zhao, Tian-Yuan,Zhou, Qi-Lin,Zhu, Shou-Fei
, p. 9692 - 9698 (2021/07/26)
A highly enantioselective Si-H bond insertion reaction of α-aryldiazoacetates catalyzed by chiral spiro dirhodium tetraphosphate was developed. Various chiral α-silyl esters were prepared with high yield (up to 92%) and excellent enantioselectivity (up to
