1095720-65-2Relevant academic research and scientific papers
1,3,5-Trialkyl-hexahydro-1,3,5-triazines-N-methylenealkylamines equilibria. 1H NMR studies in solutions
Adamczyk-Wo?niak, Agnieszka,Bujnowski, Krzysztof,Sporzyński, Andrzej
, p. 177 - 181 (2008)
The behavior of 1,3,5-trialkyl-1,3,5-hexahydrotriazines (A) in a variety of solvents was investigated by 1H NMR. A are stable for linear alkyls in deuterated solvents such as chloroform, benzene, acetone, dioxane, dimethylsulfoxide and acetonitrile. In case of branched alkyls, A are in equilibrium with N-methylenealkylamines (B). The A/B ratio depends on solvent, concentration of the sample and temperature. A react easily with methanol and lead to the formation of N-(methoxymethyl)amines (C), which are in equilibrium with B. Both the quantitative evaluation of A-B equilibrium in solutions as well as the formation of C in methanol was described for the first time.
