109582-31-2Relevant academic research and scientific papers
β,γ-Bis-substituted PNA with configurational and conformational switch: Preferred binding to cDNA/RNA and cell-uptake studies
Bose, Tanaya,Banerjee, Anjan,Nahar, Smita,Maiti, Souvik,Kumar, Vaijayanti A.
, p. 7693 - 7696 (2015)
(S,S)- and (R,R)-β,γ-Bis-substituted PNAs were synthesized from the C-2 symmetric vicinal diamine system embedded in 1,4 dihydroxybutane and 1,4-dimethoxybutane scaffolds. (R,R)-β,γ-Bis-methoxymethyl-PNA derived from d-tartaric acid was found to be in the
Efficient synthesis of (2R,3R)- and (2S,3S)-2,3-diaminobutane-1,4-diol and their dibenzyl ethers
Scheurer, Andreas,Mosset, Paul,Saalfrank, Rolf W.
, p. 1243 - 1251 (2007/10/03)
(2R,3R)-2,3-Diaminobutane-1,4-diol 6 and its dibenzyl ether 7 were efficiently synthesized starting from L-tartaric acid 1a. The crucial step, debenzylation of intermediate dibenzyloxydiazide 4, was accomplished in good yield by boron trichloride-dimethyl sulfide complex. The enantiomeric series was similarly obtained starting from D-tartaric acid.
Synthesis of new C2-symmetric bioxazoles and application as chiral ligands in asymmetric hydrosilylation
Lee, Sang-Gi,Lim, Chung Woo,Song, Choong Eui,Kim, In O.,Jun, Chul-Ho
, p. 2927 - 2932 (2007/10/03)
New C2-symmetric chiral (4S,4'S)-bioxazoles 3a and 3b, possessing chirality on their backbone, were synthesized efficiently starting from L-tartaric acid. The structure of 3a was determined by X-ray crystal structure analysis. With these novel
Synthesis of chiral 2,3-disubstituted 1,4-diazabicyclo [2.2.2] octane. New ligand for the osmium-catalyzed asymmetric dihydroxylation of olefins
Oishi, Tohru,Hirama, Masahiro
, p. 639 - 642 (2007/10/02)
Chiral 2,3-disubstituted 1,4-diazabicyclo[2.2.2]octane (DABCO) derivatives have been synthesized and utilized as a chiral ligand for the osmium-catalyzed asymmetric dihydroxylation of olefins. Optically active diols in up to 41%ee are obtained in good yields.
