1096119-97-9Relevant academic research and scientific papers
Synthesis of Reverse Glycosyl Fluorides and Rare Glycosyl Fluorides Enabled by Radical Decarboxylative Fluorination of Uronic Acids
Chen, Pengwei,Wang, Peng,Long, Qing,Ding, Han,Cheng, Guoqiang,Li, Tiantian,Li, Ming
, p. 9325 - 9330 (2020)
An efficient protocol for synthesizing reverse glycosyl fluorides is described, relying on silver-promoted decarboxylative fluorination of structurally diverse pentofuran- and hexopyranuronic acids under the mild reaction conditions. The potential applications of the reaction are further demonstrated by converting readily available d-uronic acid derivatives into uncommon d-/l-glycosyl fluorides through a C1-to-C5 switch strategy. The reaction mechanism is corroborated by 5-exo-trig radical cyclization of allyl α-d-C-glucopyranuronic acid triggered by decarboxylative fluorination.
Sonication-assisted oligomannoside synthesis
Tanifum, Christabel T.,Chang, Cheng-Wei T.
experimental part, p. 634 - 644 (2009/06/28)
We have investigated the use of sonication for the synthesis of oligomannosides. A convenient sonication- mediated glycosylation protocol that is applicable to traditional glycosylation methods has been developed. This protocol can be applicable for activ
