1096142-78-7

Basic information

• Product Name: ethyl (3-methylphenyl)phosphinate
• Synonyms: ethyl (3-methylphenyl)phosphinate
• CAS NO: 1096142-78-7
• Molecular Weight: 184.175
• Mol File: 1096142-78-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl (3-methylphenyl)phosphinate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (3-methylphenyl)phosphinate(1096142-78-7)
• EPA Substance Registry System: ethyl (3-methylphenyl)phosphinate(1096142-78-7)

Safety Data

• Hazardous Substances Data: 1096142-78-7(Hazardous Substances Data)

Upstream product

• 1335150-90-7 diethyl(3-methylphenyl)phosphonite 
• 591-17-3 meta-bromotoluene 

Downstream Products

• 1359859-96-3 3-hydroxy-4,5-bis-benzyloxy-6-benzyloxymethyl-2-[3-methylphenyl]-2-oxo-2λ5-[1,2]oxaphosphinane 

Relevant articles and documents

Revisited synthesis of aryl-H-phosphinates

A systematic study of the reaction conditions for the preparation of pure aryl-H-phosphinate esters, originally developed by Sander and optimized by Petnehazy, is reported. The influence of the reaction concentration has been investigated for the formation of phosphonite intermediates via direct addition of triethyl phosphite to the appropriate Grignard reagent. Subsequent hydrolysis of the phosphonites under acidic conditions gives various aryl-H-phosphinates in high yields and purities. Georg Thieme Verlag Stuttgart, New York.